Tuesday, January 13, 2009

Compton Scattering Paper Mislabeled? It's Obvious... Not

This installment of “It’s Obvious. Not!” looks at:

Periodical: “Physical Review” Volume: 21 Page: 483, 486
Title: "A Quantum Theory of the Scattering of X-Rays by Light Elements"
Author: Arthur H. Compton

Excerpt from page 486:

In the above excerpt, Compton discusses how to calculate the momentum of an electron that caused x-ray or gamma scattering. The momentum added to the electron is the momentum of the incident photon minus the momentum of the scattered photon.

Problem: The angle of scattering, (theta), appears to be mislabeled in the above figure vs. the usage of the angle in formula 1.

In formula 1, Compton calculates the magnitude of the electron momentum as the vector difference of the momentum of the incident and scattered photons. To subtract two vectors, you place their tails together, the resulting vector that points from the head of the second to the head of the first is the difference vector as shown below and described in this Wikipedia article.

To get the magnitude of the difference vector given the magnitude of the other two vectors, you can use the Law of Cosines and the figure shown below.

And that's just what Compton does to arrive at formula 1... almost. If you read the excerpt from Compton's article carefully, you'll see that the last term of the formula for the electron's momentum magnitude is added rather than subtracted. Per normal, this unexpected change makes the derivations further along in the paper come out quite nicely. However, if you perform the magnitude calculation with the labeled value of theta, the last term has to be subtracted, rather than added, per the law of cosines.

To make everything comes out correctly, it appears that the angle that must be used is not theta, but the supplementary angle, pi minus theta. The cosine of pi minus theta is the negative of the cosine of theta which cancels Compton's sign change in the last term. Compton may have indicated this choice of angles in the text with the phrase:

Have any thoughts on this? Please let me know. I might be wrong, in which case it would be great to find out the real explanation!

1 comment:

dark_faust said...

You're explanation seems the most likely, (-)(-) = +

IMHO: Choice of angle (or coordinates) was the culprit for most of these sign problems. This is were the professors would say, "It is a trivial exercise to show that a judicious choice of angles leads to the direct solution."